arcor - KATRING PLUS s.r.o.

Transkript

arcor - KATRING PLUS s.r.o.
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The exclusive representation
technology ARCOR
for Czech Republic and Slovakia
HEF groupe
presentation
KATRING PLUS s.r.o.
Headquarters:
Pratelstvi 1084/5, Praha 10 - Uhrineves
Czech Republic
Production plant:
Choteborska 585, Zdirec nad Doubravou
Czech Republic
Contact us:
Production: [email protected]
Sales: [email protected]
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The HEF group has a global presence
HEF
worldwide
•
•
•
•
2
55 industrial units
15 JV
Presence in 17 countries
More than 350 licences
• 1300 employees
• 144 M€ sales
• Capital owned by the
employees
• 4 research centers :
France, Germany, India,
Canada
• 60 researchers in France
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HEF is focused on Surface Engineering
Main skills
Bushings & friction components
-
Bushings
Spherical bushings
Sliding plates
Friction
components
Tribology
-
Wear
Friction
Research &
Development
Thermochemistry & diffusion layer
-
Nitriding
Nitrocarburizing
Molten Salts
Heat transfer salts
Jobbing
Wide range of coatings
upon customer request
Thin films
3
Tribological layer
Hard layer
Functional layer
Technology transfer
-
Licencing
Enginneering
Consumables
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The group organization
4
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The HEF group is the nitrocarburizing technology
worldwide leader
CLIN : Controlled Liquid Ionic Nitriding
Thermochemistry
CLIN treatments are thermochimical Nitrocarburizing and
Oxynitrocarburizing treatments wich enrich the surface of ferrous
materials with Nitrogen and a small amount of Carbon both present in
the salt
5
HEF group’s
patented CLIN
processes
• ARCOR ® : ARCOR V, ARCOR C, ARCOR N,
SURSULF,…
• TENIFER ® : TF1, QP, QPQ, MELONITE,
TUFFTRIDE,...
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CLIN : surface treatment as protection for wear and
corrosion stressed parts
Global benefits
• Very good wear resistance
• Good friction properties
• Excellent scuffing / seizure protection (adhesive wear) thanks to ceramic
charactreristics of the surface
• Excellent corrosion protection
• Good surface fatigue resistance
• Decorative black surface
• No deformation of the part
Thermochemistry
• Environmental respect thanks to "zero waste" concept
6
• No distortion → treatment done on finished parts
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CLIN provides on ferrous materials an functional
surface structure
Porosity layer :
Iron oxydes Fe3O4
Compact layer
or white layer :
Thermochemistry
Epsilon nitrides +
Iron nitrides +
Alloyed nitrides
7
Nitrogen
diffusion layer
Compound
layer
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CLIN is a flexible process requiring a suitable
equipment
CLIN process steps
Thermochemistry
Optional
8
Scope
Description
Degreasing /Rinsing
Remove oils, and other
particules from the surfaces
of the parts
Preheating
Keep a stable temperature in
the nitrocarburazing melt
Nitrocarburizing
Surface structure
Oxidizing
• Corrosion protection
• Black aspect
Cooling / Cleaning
Remove salt from the surface
of the parts
Mechanical finishing
• Smooth surface
• Low roughness (no lower
than before treatment)
• Friction properties
HEF has know-how in :
• Shot blasting
• Tribofinishing
• Centerless polishing ...
Impregnation
• Improve corrosion
resistance
• Bright aspect
HEF impregnation used :
• Corolac (dry aspect)
• Corofluide (oily aspect)
The iron nitrides (Fe0) composing
the porous outside layer of nitrided
surface will be changed in stable
iron oxydes (Fe304)
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A few CLIN parameters influence surface structure
results
The following parameters :
•
•
•
•
•
Material
Treatment temperature
Treatment time
Bath chemistry
Bath cleanliness
(type, roughness, shocks, rust, machining, …)
(easy to control in CLIN process)
(easy to control in CLIN process)
(daily regenerated, and periodictly controlled)
(Periodically cleaned)
Thermochemistry
influence
9
The following parameters :
•
•
•
•
Compound layer thickness
Diffusion zone depth
Surface hardness
Corrosion resistance
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Alloying elements influence CLIN surface structure
results
At constant treatment parameters, an increasing content of alloying element
causes :
• Decrease in thickness of the compound layer
• Decrease in nitrogen diffusion depth
Thermochemistry
• Increase in surface hardness
10
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CLIN : Taylor made nitriding solution
ARCOR C
ARCOR V
ARCOR N
From 530°C to 570°C
From 500°C to 590°C
630°C
Thermochemistry
• Shorter treatment time
→ more economic
11
• More porosity →
better friction
properties
• Better corrosion
protection
• Better wear
protection
• Lower increasing of
roughness
• Nitogen austenite layer
(soft layer) below the
compound layer
• Cracking protection of
the compound layer
under flexion
• More ductile layer
• Less diffusion (thin part)
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Thermochemistry
CLIN is a flexible process requiring a suitable
equipment
12
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Thermochemistry
Manual line assisted by computer
Software developed by HEF
13
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Manual line assisted by computer
Benefits of the software
• Processes (Ex ARCOR BVGD2-5) are defined in the software
• Control of process parameters (alarms)
• Actions (changing of step) are announced by the computer
• The action is manually done by the operator (hoist)and
validated on the computer
Thermochemistry
• Each action is recorded (Time, process parameters,…)
14
• Water is automatically added in the rinsing cascade after each
load passage (minimize consumption of water)
• Internet connection possible from HEF headquarter
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Quality controls in production
Process parameters controlled :
•
•
•
•
Treatment temperature
Treatment time
Bath chemistry
Bath cleanliness
(controlled by computer)
(controlled by computer)
(daily regenerated, and weekly checked)
(Periodically cleaned)
Thermochemistry
Checking of the reproductibility of the process ARCOR (on part of the
load) :
15
• Surface hardness
• Compound layer thickness
• Diffusion depth
Twice a week in production
Daily during the ramp up
A chemical and metallurgical laboratory is
setted up together with the production line
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Thermochemistry
ARCOR standard production line
Example
16
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Thermochemistry
CLIN treatments are applied in various industries
17
Automobile / Truck
industry
CE / Agriculture /
Hydraulic indutry
Railway / Aviation /
Urban transports
indutry
Platform lift /
Handling / Joints
indutry
Steel / Aluminium
industry
Forging industry
Energy / Oil & Gas /
Off-shore indutry
Weapons indutry
Electrodomestic
Equipments
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CLIN treatments & Applications
Friction & Wear
resistance
Thermochemistry
Seizure
resistance
18
Engine valves, Crankshafts,
Differential bodies,…
Differential pins, Rocker arms,
Rocker arm shafts,…
Alternative to
hard chromium
Engine valves, Gas spring, Shock
absorbers, Cylinder rods, Brake
system pistons & sleeves,…
Corrosion
resistance
Wiper shafts, Washing machine
shafts & tubes, Joint pins,…
Mechanical
resistance
Latch door plates, ball bearings
cages, stamped parts,….
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Thermochemistry
CLIN treatments are applied in Automotive / Truck
industry
19
Powertrain /
Engine
Ball studs /
Steering
Body
equipment
Gear box /
Transmission
Shock
absorbers
Gas spring
Bearing
Brake systems
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Thermochemistry
CLIN treatments are applied in Powertrain / Engine
industry
20
Cylinder Liner
(truck)
Common rail
cam rotor
Rocker arm
Rocker arms
shaft
Crankshaft
Valve
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CLIN treatments in hydraulic brake systems
Thermochemistry
Brake rotors
21
Pad supports
Brake grip sleeves
Brake pistons
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CLIN : surface treatment as protection for wear and
corrosion stressed parts
CLIN Vs gas nitriding
+++
---
• Reproductibility (gas nitriding parameters: parts
Thermochemistry
quantity, parts cleanliness, gas volume in furnace,...)
• Uniformity (homogeneity of temperature and
chemical composition of the salt)
22
•
•
•
•
•
•
•
•
Better corrosion resistance
No fragile white layer (thanks to Epsilon nitride )
Better wear resistance (thanks to Epsilon nitride )
Less distortion risk (because of gradual cooling)
Shorter cycle time (highest nitrogen potential)
Stainless steel depassivation efficient
Less polluting
No unintentional masking (all the part in contact
with salt)
• Cleaning results do not play a such important
role
• Masking difficult
• Impossible treating large
components
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HEF group
Alternatives
to hard chromium plating
The creative force
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European environment legislation
concerning the different chrome compositions
Chrome compositions
Applications
Limit of use *
-
-
Hard chromium plating
Sept. 2017
Anhydrides
Textile, Paint, Tannery,…
Sept. 2017
Dichromates
Textile, Paint, Tannery,…
Sept. 2017
Trivalents (CR3+)
Hexavalents (CR6+) :
-
24
Chromium trioxide (Cr03)
Chromic acid (H2CrO4)
* defined by the CE regulation n°348/2013
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Hard chromium process
Schema and Cr6+ polluted wastes
Cr6+ contamination
in the atmosphere
Cr6+ contamination
in the rinsing water
Cr6+ contamination
on the masking and
fixturing
Component
chromic acid
H2CrO4
- Power +
Cr6+ contamination
in the sludge
25
Anode
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Hard chromium process
Chromic acid (H2Cr04) description
directive 67/548/EEC
•
•
26
Hexavalent chromium compounds (including chromium trioxide,
chromic acid) are genotoxic carcinogens.
Chronic inhalation of hexavalent chromium compounds increases the
risk of lung cancer.
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Alternative to Hard Chromium plating with Cr6+
Alternative processes
Advantages
Hard chromium plating
with trivalents (CR3+)
-
-
Non Industrial process
-
-
Cost
High layer thickness
Grinding after coating
Small capacity
-
Cost
No corrosion resistance
Thermal spray coating
27
PVD coating
-
Uniformity of the coating
Nitrocarburizing
-
Corrosion resistance
Wear resistance
No surface flaking
Surface mechanical resistance
Disadvantages
-
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The HEF group is the nitrocarburizing technology
worldwide leader
ARCOR treatment is a thermochemical Oxynitrocarburizing
treatments which enrich the surface of ferrous materials with Nitrogen
and a small amount of Carbon both present in the salt, and which
create on the external surface of the material a hermetic iron nitrides
layer offering high corrosion resistance, good friction properties and
wear resistance.
ARCOR V®:
28
Standard process
ARCOR BV® :
With a final polishing step offering a low surface roughness and
a bright black aspect
ARCOR PV® :
With polishing and a final post oxidation step offering a low
surface roughness and a uniform black aspect
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Hard Chromium Vs Nitrocarburizing
Salt Spray Test (SST)
29
* ISO 9227 / ASTM B117 / DIN 50021
** Realized on XC45 steel / AISI 1045 with surface roughness Ra <0,8
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Hard Chromium Vs Nitrocarburizing
Metallographic comparison (XC45 steel)
Hard chromium plating : 30 µm
XC45 steel / AISI 1045
30
ARCOR BV : 20 µm
XC45 steel / AISI 1045
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Hard Chromium Vs Nitrocarburizing
Surface hardness & Hardness profile
Layer thickness
µm
Layer hardness
Hv0,025
Surface hardness
Hv1
Surface hardness
Hv5
ARCOR BV
≈ 20
≈ 850
≈ 470
≈ 445
Hard chromium
≈ 30
≈ 1100
≈ 560
≈ 380
Hv
L
a
y
e
r
mm
31
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Hard Chromium Vs Nitrocarburizing
Friction properties – Description of test bench *
* Tribological studies done by IREIS
N
Seal /guiding
material
Surface treatment **
Alternative motion
** Surface roughness :
Hard chromium/ Ra 0,045 – R max 0,422
ARCOR BV / Ra 0,068 – R max 0,485
XC45 steel
32
Motion :
Alternative rectilinear
Travel :
70 mm
Linear speed :
0,1 m/s
Contact pressure :
2 MPa
Number of cycles :
4000
Oil :
Hydraulic fluid
Viscosity @40°C : 18 cST
Density @15°C : 0,83 g/cm3
Surface tension @20°C : 27,0 mN/m
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Hard Chromium Vs Nitrocarburizing
Friction properties – Wear results
Friction couples
33
Wear on the polymer part
PTFE / Hard chromium
10 µm
PTFE / ARCOR BV
10 µm
Fluorinated elastomer / Hard chromium
80 µm
Fluorinated elastomer / ARCOR BV
50 µm
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Hard Chromium Vs Nitrocarburizing
Summarize of ARCOR treatment advantages
ARCOR process Vs Hard chromium plating
+++
•
•
•
•
•
Higher corrosion resistance in Salt Spray Test (SST)
Similar corrosion resistance in Copper Accelerated Acid Salt Spray test (CASS)
No risk of failure due to hydrogen embrittlement
Cr 6+ free (toxic hexavalent chromium) – No concerned by REACH
No peeling nor flaking (because the layer becomes an integral part of the base
material)
•
•
•
•
•
•
34
No micro cracks
No grinding after treatment
Dent resistance thanks to the ductile surface
Mechanical surface resistance thanks to the Nitrogen diffusion
Better lubrication retention thanks to the external porosity surface
Similar seals and guiding components than for hard chromium plating
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Conclusion
Conclusion
Thank you for the meeting.
Do you have any question ?
35

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