vm. CHEMISTRY
Transkript
vm. CHEMISTRY
-- -- --- vm. CHEMISTRY- CHEMIE --- - - - - TO READ CHEMICAL ELEMENTS IN ENGLISH ============================================== HOW a,ymbol Atomic Number Name 1n Czech 1n English Ac 89 Actinium Ag Al 47 13 Silver I's;lvaI Aluminium' I,a:!lju'minjamI am.: Aluminum StHbro Aluminium Americium Americium Am 1~k'tiniamI Aktinium Iame'risiamI A 9$ lB As )) Argon I a:.ganI Arsenic'I'a:snik1 Argon Arsen At Au 85 Astatium 79 Gold I' gouldI v n~zvech slou~enln Astat(in) Zlato B Be 5 56 4 B1 8' Bk Br 97 Be C C8 Cd Ce Cf Cl Cm Co Cr Cs Cu )5 6 20 48 58 98 17 96 27 24 55 29 Dy 66 En, Es Er 99 68 6) 9 26 Eu F Fe Fm Fr 100 87 , . Boron Barium . las I'bo:ronI . , , teit1amI t~!: Aurum , I o:ramI Bor . I bearlamI . Beryllium lba , Baryum Beryllium Vizmut r111amI Bis~uth 1'bizmaeI . ,. Berkelium 100.: kelljamI Bromine I'broumi:n (-sin)I Carbon I'ka:benI . ., Calcium I ~8i9mI Uhl:(k V~pnik Kadmium Cer 1'piariamI Californium Chlorine Curium Cobalt Brom I'kredmiamI Cadmium Cerium Berkelium Kaiifornium I,krell'fo:njamI I'klo:ri:iu Chlor Curium 1'kjuariamI 1ko'bo:ltI Kobalt , . Chroanlum I kroumiamI Chrome 1'kroumI Caesium I'si:ziamI , Copper I kopaI Cuprum I.'kJu:pramI Chrom . Dysprosium Idis'prouziamI Einsteinium Iairi'stainiamI Erbium I'a:biamI Dyprosium Einsteinium Europium Fluorine Europium Fluor , 1jua'roupiamI I'fluari:nI Iron I aianI v n~zvech slou~enin Fermium Francium Erbium I'fa:mjamI I'~siamI U!: Ferrum , ~elezo I feramI Fermium Francium S.ymbol Ga Gd Ge Atomic Number H :n 64 J2 I He 2 Name in English in Czech Gallium r'liamr Gallium Gadolinium Gadolinium Germanium r,da'liniamI Germanium rdze: 'meiniamI Hydrogen I'haidridzanI Helium I'hi:liamI Vodik Helium Hi' 72 Hafnium I'ha:fniamI Hafnium. Hg Ho 80 I'ma:kjuriI r 'houlmiamI Rtut 67 Mercury Holmium In 49 Indium r'indiamI rr I K Kr La Lw 71 53 19 36 57 103 Li J Lu 71 Md, Mv Mg Mn Mo N Na Nb Cb Potassium Ipa'ejamI Krypton I'kriptanI .Draslik Krypton Lanthan Lanthanum. r'lrenganamI Lawrentium 1,10: 'rentiamI 12 25 42 Lithium Lutecium Lutecium llu'ti:§iamI I,menda'll:viamI Mendelevium Magnesium Ioreg'ni:ziamI Magnesium Manganese r/a'ni:zI Maan Molybden Dusik Molybdenum 7 Lawrentium- Lithium I'ligiamI Mendelevium Ima '11bdinamI r'naitridzanI Nitrogen - Indium Iridium Jod Iridium rai'ridiamI Iodine r'aiadi:nI 101 I Holmium 11 Sodium I'soudjamI Sodik 41 Niobium Niob. insi'9ubiamI . Columbium Ika lambiamI Nd Ne 60 10 Neodymium Inia'dimiamI Neon I'ni:onI . Neodym Ni 28 Nickel Nikl No 102 93 8 76 15 91 82 Np 0 Os P Pa Pb I' niklI . Nobelium Neptunium I Inep.'tju: niamI Neptunium Kysl!k Osmium Fosf'or Protaktinium Olovo Oxygen I'oksidnI Osmium I'ozmiamI I'f'osf'arasI Phosphorus , , Protactinium I prouk tiniamI Lead I'led! 46 Palladium Pm 61 Prometheum Po Polonium Pu 84 59 78 94 Ra 88 Radium Rb 'J1 Rubidium Pr pt Nobelium I,nou'bi:liamI v nazvech sloucenin tz: Pd Neon . Ipa'leidiamI Ipra'mi:giamI . , Ipa louniamI Praseodymi um . , , I,prreziadimiamI PIa tinum I p1retinamI Plutonium Iplu: 'tounjamI I'reidiainI Iru'bidiamI , . Re 75 Rhenium I ri:niamI Rh Rn Ru 45 86 44 Rhodium I'roudiamI , , Radon I dan, reidanI Ruthenium Pumbum I plambamI Iru: 'giniamI Palladium . Prometheum Polonium Prazeodym Platina Plutonium Radium Rubidium Rhenium Rhodium Radon Ruthenium C I ! mhol Atomic Number Name in English 1 16 lib '0 51 21 "0 '14 J4 14 "11\, 62 Samarium 50 Tin I'tinI v nazvech slouenin.t: So IIn .:in Czech I'salfaI Sulphur Antimony"A I'rentimanlI Sira Antimon Scandium Selenium Skandlum Selen Silicon I'ska!ndjamI Isi 'UnjamI I'sllikanI Kremik Isa'ma:riamI Samarium Cin Sannum I sta!namI .., J8 Strontium 'r 7J Tantalum 65 43 Terbium Technecium Thorium Titan. I'atronUamI Stroncium Tantal I'trentalamI '1'0 52 Terbium I'ta:biamI Technecium Itek'niiamI Tellurium Ite'ljuarlamI '1'1' 'JIJ. 90 22 Thorium I'eo:riamI Titanium Itai'teiniamI '1 81 Thallium 'JIm 69 U 92 2J '1'1) '1'0 V 74 54 J9 70 JO 40 VI X. y YtI In ,... I' , Tellur l1amI Thallium Thullium I eju:l1amI . Uranium Ijua'relniamI Vanadium Thulium Uran Vanad Iva 'neidiamI Tungsten I'tapstanI Xenon IizenonI Yttrium I'itriamI ytterbium U'ta:biamI Zinc I ' zipkI , . Zirconium. Iza kouniamI Wolfram, Tungsten Xenon yttrium Ytterbium Zinek Zirkon 9 POZNAMKY KE lSTENl CHEMIrnCH SYMBOLttA N1zvtt V ANGLIlSTIm: ======================================~========================== Zneky ehemickych prvIro se Hou i>odobn~ jako pismena ., I I ° I ouI; H I ei~I; S I esI; Stoji-l1 2 H20 pI'>ed zna~kou prvku - . two molecules Znam~nka + H + md~e znamenat molekuly ", a zna~ kladnou univalent positive napr.:. nebo moly, napf.: of H20 av ei~ tQ: , I tu: , . mol1kjulz ", I tu: moulz av ei~ tu: ouI - two-moles of H20 i . ~islice," angUck~ abecedy, , , Si I as ail ouI a zapornou valenei iontu: , , , hydrogen ion I,juni veilant pozitiv haidrid~an 'aianI jednomocny kladny iont vodiku divalent po~itive copper ion dvoum.ocnykladnY iont m~di Al+++ , ~dai veilant , , pozitiv tervalent (trivalent) positive aluminium ion , , ,--, (tre.iveilant) pozit1v ,relju minjam aianI ,. , koper aianI Ita: 'veilant trojmocnY kladnY iont alumin1a D CI- - negative univalent chlorine ion I'negetiv , aianI dporn! juni'vellent 'lclo:r1:J' jednomocnt font chlora 4)Dal~:Cmocenstv:C se vyjadfuje pomoc1:pf':Cslu§n~ pfedpony .18 , , ,+-'Valeni. Pfbvuk v!dy na slovA "valent", napf.: tetraItetre-I tetravalent penta- Ipenta-I pentavalent tetravalent Itetra ~~cnt p~timocnt hexa- Iheksa-I hexavalent- i!lestimocn~ heptaoct~- Ihepte-I Iokta-! heptevalent octavalent sedmimocn~ osmimocnt 5) Zna~ka NH2 cAt2 6) Znak - vellentI znamenli vazbu med atom.y a n8~t8 S8: bond be"tween nitrogen and carbon atoms I 'bondbi 'tn: n 'nei tridlen end 'p: ban 'tetamzI + znamenli: plus I' plasI together with Ita , ge~ 'fibI give I'givl form !' f'o:-mI give I' g1v:r 9) Znak ~ znemen4: e de"!' tvof1 , pass over to I'pa:e lead to p1~ epolut I'litd tal daj.t ouva tal pfechlizej:C vedou k ' :forme I' fo: mzI is formed Iiz' to: mdI - do tvof:! -- tvof:C se,. vznikne 10) Pro l§ten:l n~kter!ch t.yplck1ch pHpon v ntizvech chemick!ch 8lou~enfn nen:C momo etanovi t ~asto jednotnou vyslovnost. Jednak se zde uplatnuje profesioMln:l v!elovnost, usus, jednek vIi" celkov~ch v~810vnostn:Cch,tendenc1 anglil§tin.yt jednak md!e p6so:t>1t i vl1v amer1ck~ angl1~tin.y. Pro jednu p:Uponu lze, proto' ~a8tonaj:(t 1 n~kol1kerou _v~slovnost. Raprv4m m:(sU je uvedena v~slpvn~st pro chemiky nejbUri~ji!l:(, 1 kdy~ se n~kde lU:( od bUn~ vyslovl1ost1. " chemick1.usus pf:Cpone bri t. -ene acetylene, I-l:nI eth,ylene,'fluorene, I-elnI -ane butane, propane, methane -i te fluorite, -lne I-l:nI ~-~:nI napthalene, I -einI I-al tI ,chlorite, eulphite -yl I-ill am.yl" benzyl, methyl, ethyl Je zde ~ast4 kol:Cst1n:l1-111 I-l:nI pyrldlne" fluorine, benzine chemick~ usus am. b~!nIi ~slovno~t toluene, 10.2. 10.'. - I-ait;[ ]:-ai tI I-al11, lo.-i. I~i:nI benzene 10.4. 1-111 a I-alII. I-ainI eth,ylamine, phosphine, I I-i:nI bromine, chlorine, " I-ainI aniline, m~thylamine, iodine U n~kterych nt1zv6 v!elovnoet kol:Csti. U n~kter~ch benzlne -lde - ~vojic md!e docht1zet pro toto!nou benzene fluorine I-aidI; U:dI I-ald! ' vyslovnost k nejasnostem: fluorene - 10.5. iodine . chpm1ckj pHpona usus b~~nd v1s1ovnost hrit. chemicky ueu8 em. I-idI Vjs1ovnostI-61~I byv~ u nnorp~n1ckycha orgnnlckych slou~enin.I-i:dI u nAkterych orFsn1ckych91ou~enln.hI. nn -amide. I-aidI hydr1de, chloride, iodide, peroxide, sulphide. oxide. bromide. hydroxide, sAchar1de f1uor1de, nitrnmide. trifluoride 1-1: dT -ate I-itI; J-(:itI J-eHI; I-it! I-eit!; I-itI I-e1tI 10.7. per:'ful.,lInte. sulphate I-itI; I-eitI acetste. perchlorate. potassium chlorate. dichromate, carbonate Vjslovnost velmi kol!e~. II) P~fzvuk u slov bez pfedpon byv~ na po~~t~u slove, napr.: 'cadmium, 'fluorine, "sulphite. 12) Np.ptfzvl1~n~ slabiky se ~asto neredukuJ!.napf.: phenol I'fl:nolI, boron I"bo: ronI. 1)) Pfp.dpo~yjeou ~eeto bez (hlevn!ho) pfizvuku: dioxide Jdal'okealdI, monoxide Imo'noksaldI, tr'bromlde Itrai'broumaldI, tetraoxide Itotr'okssidI, subsulphide Issb'salfa1dI, hydroxide Ihai'drokseldI 14) P~fpony: -ncic. -alie. -anlc, -arie, -elic, -enle, -eric, -etic, -idic, -ilic, -inic, -islc. -ic: -onic, carbonic Vyjimka: -opic, -oric Ika: 'bonikI, I'klorlkI a) acetic IA'slstlkI, cetlc Isl:tikI, cerie IslsrikI b) ptidavn~ jm~n8 odvozen~ od nenesyeenych uhlovodanO 15) Ptfdavn~ jm~na zakon~en~ ne -lc ce predeh~zejtei -lc: 16) Slovo maJi ve vyslovnostl kr~tkou samohl~skupfed ehlorie valent pentavalent carbonlc maji pfizvuk na pfedposledni sloblce, tj. alabl~ , Ika: bonikI, ehloric I klorlkI ve spojeni s pfedponam1 je v~dy pfizvu~n~: Ipenta'veilantI 17) V omerick~ a britsk~ anB1l~tln~ mohou byt odchylky v pravopise jednotl1vych Blov, nRp~.: aluminum aluminium am. brit. protoactinium protactinium zJednoduAuje se ou f ( Bulfite) skuplna -ph- (sulphlte) 10 ANOLICKA CHEMICKA NOMENKLATURA ===:=====::==:======::========== KY8ll~niky (Oxides) P~i tvoteni ndzvu ky8li~niku je dOle~1ty pfedevAim po~et kysli~nikO, ktery je da- ny prvek schopen tvotit. 1) Tvof!-ll prvek pouze jaden ky8li~nik, pak ns prv~m mistA v n~zvu je n~zev dan~ho prvku, katlontu, s to bez zm~~y (bez ohledu ns mocenstvi prvku) a na druh~m mist~ vjraz "~" I'oksaidI Al20) - aluminium oxide (kys1. h1inlty) ~ 2) Jestli~e danY prvek m~~e vytvotit cenetvi: a) ptedponsmi ,mon(o)- kysli~n!kO ne~ jeden,.roz11!ujeme mo- I'mona-, 'mono-, 'monou-1, " ~- 1dai-1, !£!Itrai-1, , hex(s)- 1 hekea-, tetr(a)- I tetra-I, pent(a)- I penta-, pen ~-1, hek ,~1, hept(a )' - I heptaw, hep ,~-1, oct(a)jujeme v jedno slovo a vYrazem oxide r'okaaidI N02 - n1trogen ~ox1de I "okta-, ok ~I, (kyal. due1~1t$) N20, - n1trogen !£10x1de (kyal. dueit$) N205 nitrogen pentoxide (kysl. dus1~nY) -~ b) ptiponam1 - kter~ epo- I-asI (pro ni!!i mocenstvi)a -1£ 1-1kI (pro vy!!i mo- ~_ censtvt), kter~ ptipojujeme k n'zvu kationtu bua pro roz11!en! kysli~n!kO pu R20 a RO nebo tehdy, netvoti-li danY prvek vice ne! dva kysli~niky. Tyto ptipony lze pf1pojovat pouze k latinsk$m n4zvOm prvkOa N20 NO c) predponou - nitrous oxide nitric oxide sesQui- I'aeskw1-1 (kysl. duanY) (kysl. dusnat$) k n'zvu oxide pro ozna~en! kysli~k~ ~pu R20J: M~O, - manganese sesquioxide (kysl. mangan1t$) d) pfedponou ~I'sab-I nebo ~I'hemi-1 pro ozna~en!kys11~n!ku s ni!!im mocenetvim net je u dan~ho prvku b6!n~: Pb20 e) pfedponou perH202 ,) Kysli~niky s dvoji lead suboxide,lead hemiox1de - 1pa-1 - nebo super- 1'sju(:)pa-I Qydroxen"peroxide, hydrogen auperoxide valenci prvkO (kya11~nik K y s e 1 i n y se ozna~uji ferriferrous Fe,04 k ozna~en! pero~dO: oxide, spojenim nazvu ferrosoferric ~bou kysli~n!kO: ox1de !eleznato-!elez1t$) (Acids) 1) ~sel1nY bezkyslikat~ tvotime: a) pfiponou -~ I-1kI a vYrazem HCI HJ "acid" - hydrochloric ac1d - Qydro1od1c ac1d I'~s1dI: (kys. chlorovodikov4> (kys. jodoyodikov4) b) nebo je pova!ujeme za slou~en1ny vodiku a tvofime n4zev obdobnA jako u kysI1~nikO: HCl HJ - hydrogen chloride (chlorovodik) - hydrogen 10d1de (jodovodik) 2) KYselinv kysl!kat~: pro vytvofen! n'zvu je op~t rozhoduj!c! po~et mo!njch kyse11n: a) pokud existuje pouze ~edns maIn' kyse11ns, tvot!me n4zev pfiponou H2CO, - carbon1c"scid -1£ 1-1kI (kys. uhl1~1t') b) pokud jsou mo~n~ pouze 9!! kyseliny, obdobnA jako u kysli~nikO pf!pons -~ I-asI ozns~uje n1!!i kyselinu, pt!pona -~ I-1kI ozna~uje vyAAi kyselinu: HN02 - n1trous acid (kys. dusit'> HNO, - nitric acid (kys. dusi~na) c) pokud denY prvek tvoti vice ne! dv~ kyeeIi~, pro nejni!A1 kyselinu pou!1jeme vedlep~1po~ -oue I-~8I jeAt~ ptedponu ~~ I'heip~u-I, '~ro nejvyAA1 vedle ptipo~ -lc I-ik1 p~edponu per- Ipe-I: HCIO - hypochlorous acid (kys. chlom4) HCIO, HCl02 HCl04 chlorous ecid chloric acid perchloric ecid d) oMobn~ jakov ~esk~m n4zvoslovi , " QrthoI oQa-, oQou-, 0 90-1, (kye. (kye. (kys. pou!iv4 angl1~tlna , BD:2,- I pairou-1, HPO, - metaphosphoricacid H,P04 - H4P207 H,PS. H4P206 Z 4 /I 8 ~ Y - - chlorit4) chlore~n4) chlorist4) (kys. met8fosfore~n4) acid (kys. orthophospboric pyrophosphoric thiophosphor1c hypophoephoric pfedpon m!1RI'mete-I , ~I QaiouI acid acld acid (kye. (kys. (kye. orthofosfore~n') pyrofosfore~n') thiofosfore~n') hypo1'oefore~n') (H.y~roxide8) Ang11ckj vtraz hYdroxide ee obdobn~ jakeu kya11~n!kO epoJu- Iha1'droks81dI jet 1) " nezm~n~n1mn&zvemk$tiontu, pokud existuje pouze ~ z'eada: (hydrox1d eodn1) NaOH - sodium hydroxide 2) prvek dostane pfiponu -ous I-esI nebo -1£ 1-ikI krozl1Aen1 nil!1hoe vyAAiho mocenetv1: Fe(OH)2 - ferrous Fe20,.H20 - ferric hydroxide hydroxide ,) u n~kter,!chz4sad 8e d08Ud pou!!vej! star!i I'ko:stikI (!1rev'!): "caustic" NaOK - CQustic sode KOH S 1 0 1 i - (hydrox1d !eleznat,!) (hydroxid !elez1t'!) n4zvy, vytvofen4 pomoc! vf,rezu caustic potash (!1rev,!natron) (!:(rav4 dre.slo) (Salts) . 1) SQ11 bezkye1:!ket1ch 08el1n: provytvofeni jejich n4zvu rozhodujepp~t po~et mo!ntch sol:(: 1. U kat10ntd,vytv4feJidch bHn~ adl jen v .1ednommocenstvi, tvoH 88 n4zev' oMobn~ jako u ky811~n!kd: kst10nt zOst4v4 baze Z~I\Y a n4zev vytvofime z aniontu pfid4n1m koncovKy -ide 1-a141: NaCl - sodium chloride (chlorid80dn$) 2. Tvof1-li kstiont eoli 8) pfipoJuJeme pfedpo~ !t!Itrai1 std.: FeS - FeS2 - b) nebopf1po~ FeC12 FeCl, d) -oue - 0 mocenetvich, pek steJnl Jako u kys11~n1kO , , , mono- I mone-, mono-, monou-I, ~Ida1I, rOzn,!ch ironmonosulphlde(s1rnik!eleznatt) 1ron dieuIph1de (sirn1k !e~~U1tf/:.U~7>. I-esl a -1£ I-1kI k n4zvu kationtu: ferrous chloride (chlor1d !eleznat,!) ferric chloride (chlor1d - iron (III)-chloride 0( . ~imskou ~islic1: (chlorid !elezit,!) , vr' -?1.::~.~/ !elez1t,!) mocenstv! kovu ve 8lou~enin~je mo!no t~! ozns~it pfeen~ FeCl, . 2) 5011 kyslikat~ch kysel1n: tak, z ozna~eni n~zev vytvotime -ous -~ I-asI zam~n!me p~iponou -1!! I-aitI, p~!ponu -ie I-ikI p~!ponou I-itI, pti~em! zachovavame i ptislu!n4 ptedpony hypo- a perhypochlorous acid - hypochlor11! (hypoehlorit) ch10rou8 acid chlor11! (ch1oriten, chlorit) !e vyjdeme chloric perch10ric acid acid - odpovidajicich ~8elin chlorate perch10r~ a p~iponu (chloreenan, ehlorat) (ch10ristan) 11 HOW TO READ CHn.!ICAL FORMULASOF INOmANIC . , Aluminium bromide NH4C02NH2 NH40H Ammonium carbamate 1a'mounjam 'ka:~eltI , , Ammonium hydroxlde Ia mounjam SbBr, SbC15 Antlmo"1 tribromide Deutero ammonia I,ooljuminjam broumaidI I,~lju'minjam 'klozraldI ~ I'dju:tara a'mounjaI Chlorld hlinit'J hlinlt'J -'d- hal droksaldI , Bromid Deuteroamoniak, amonlak Karbamiden amo~ l;Iydroxid amo~ (epavek) , . . I oontimeni trai broumaldI , AntimO"1 pentachloride EXAMPLES , AlBr, AlCl, ND, Alumlnium chloride COMPOUNDS , Bromid antlmonity I oontimani ,penta klozraldI Chlor1d antimoni~n'J SbI, Sb20, AsBr, AsH, Be12 BiBr, BBr, CdO Antimo"1 tr1iodide l'oont1mani tra1'aiada1dI Antlmo"1 trioxide l'oontimani trai'oksaldI Areenic tribrom1de Ia: 'senik trai'brouma1dI Arsine I'a:si:nI Jodld antlmonity Kys1l~nik antimonity Bromid areenit'J Arsenovodik Beryllium iodide Iba'rl1iam 'aiadaidI Bismuth tr1bromide I'bizmaQ trai'broumaldI Boron trlbromide I'bo:ron tra1'broumeldI Jodid berylnaty Cadmium oxide Kysl1~n!k kademnaty Ca(OH)2 CaCO, Ca(HCO,)2 Calclum hydroxide Calcium carbonate C02 CO Carbon dioxide C,02 CS2 COO12 C120 CI02 C1206 I'kOOdmiam 'oksaidI I'~lslam I'~lsiam Calcium hydrogen carbonate 'haidrid!an 'ka:ban1tI hal'droksaldI 'ka:banitI I'~lsiam Kysli~n!k uhelnaty Suboxid uhliku I'ka:ban mo'noksaidI I'ka:ban 8ab'oksaidI " Carbon dlsulphlde Hydrox1d vapenaty Uhli~ltan vapenaty Kyee1y uhli~itan vapenaty Kysli~n!k uhl1~1t'J I'ka:ban dal'okaaidI Carbon monoxide Carbon suboxide Bromid blzmutit'J Bromld bor1t'J , I ka:ban dai salfaidI Slrouhlik , Phosgene I fosd!i:nI , , Chlorine monoxide I klo:ri:nmo noksaidI , , Fosgen Kysll~n!k ehloroy Chlorine dioxide Kyeli~nik chlorl~lty , I k10:ri:n dal oksaldI , , Dlchlorine hexoxide Idal klo:ri:n heks oksaldI Kysli~n!k ehlorovy C1207 Cr(CO)6 Chlorine heptoxide I'~lo:ri:n hept'oksaidI Kyeli~nik chlorlsty Chromium hexacarbo"1l I 'kroumiam ,heks9 'ka:banllI Hexakarbonyl chloru Cr02C12 CoC12 Chromyl chloride I'kroumil 'klo:raidI . Cobaltou8chloride Iko'bo:ltae 'klo:raidI Chrolll31chlorid Chlorld kob~ltnaty , , I kju: pras broumaidI I'ferik 'klo:raidI Cuprous bromIde Ferric chloride Ferrous chloride I'feras 'klo:raidI Bromid ~~anY Chlorid !elezity Chlorid leleznaty Chlorovod:lk Hydrogen chloride I'haidridlan 'klo:raldI Hydrochloric acid I'haidrou'klo:rlk '~sldI Hydrogen fluoride Hydrofluoric acid I'haidrid!an 'fluara1dI Fluorovodik I'haidrou'fluorik '~sldI Kysellna £luorovodikova Hydrogen peroxide I'haidrid!an pa'roksa1dI Peroxld vodiku Sirovodik Hydrogen sulphide I'haidrid!an 'salfaidI , , Lesd sulphide I led salfaidI Lithium hydroxide I'li9iam hai'droksaidI , , Manganous chloride Imoop~nas klo:raidI , , Mercuric chloride lma: kjuarik klo:ra1dI Ni tri'c oxide I' na1 tr1k Kyse11na chlorovodikov6 Sirnik olovnaty Hydroxid 11thnY Chlor1d mangan1~lty Chlor1d rtutnaty 'oksaidI Kysl1~nik dusnaty I'naitras 'oksaidI Kysl1~nik dusnY , , . Dinitrogen tetroxide Idai naitridlan tet roksaidI Nitrous oxIde Kys11~nik NOCI r H, Nitrosyl chloride Phosphine I'naitrasil 'klo:raidI jS1H4 S102 AgCl ,NoBr Na-2CO, NaCl NeOH Ifos'founiam 'klo:raidI SO, H2S04 H20 chlorid, I'silikan dai'oksaidI Kysli~nik ktemi~ity Silver chloride I'silva 'klo:raidI Chlorid stribrny Sodium bromide I'soud1am 'broume1dI Ibai'ka:banitI Sodium carbonate Sodium chloride Sodium hydroxide Bromid sodnY Kysely uhli~itan sodny I'soudiam 'ka:ban1tI I'soudiam 'klo:raldI I'soudiam hai'droksaidI Sulphur dioxide I'salf& dai'oksaidI Sulphur trioxide I'salfa trai'oksaldI , , Sulphuric acid Isal fjuarik ~sidI Water I'wo:taI S02 Fosfonium Silan Silicon dioxide Bicarbonate NaHCO, Nitrosylchlorid Fos£on I'fosfi:nI Phosphonium chloride Silane I'saileinI H4Cl dusi~lty Uhl1~i tan sodnY Chlorld sodny Hydroxid sodnY Kysli~nik s1ri~1ty Kysll~n:lk sirovy Kysel1na s:lrova Voda 12 - HOW TO READ CHEMICAL FORMULAS OF ORGANIC COMPOUNDS EXAMPLES ================================~==========================~=======:== Dichlormethane Idai'klo:rou'mi:eeinI Formaldehyde Ifo:'~ldihaidI Formic acid I'£o:mik '~sidI Methane I'm1:eeinI; Methanol I'meQanolI I'meeeinI Methylamine I'meGil 'eimi:n, 'mi:eail ~i:n,- 'meGil eimainI Acetylene Ia'setili:nI Acetonitrile Ethylene I'res1tou'ne1trailI I'eQ11i:nI Acetaldehyde I'resat'~ldiha1dI Dlchlormethan Formaldehyd Kyselina mraven~i Metan Metanol Metylamin Acetylen Acetonitrll Etl\.vlen Acetaldehyd Acetic acid 1a'sl:t1k 'resld1 Ethylamine l'eell'remlsnI 1'1:ga11-1 Acetone 1'reeltounI Kyael1na octov~ Ethylamln Aceton Propane I'proupelnI Propene I'proupl:nI Propylene I'proupl11:nI Propan Propen Propyne Propln Propylen I'proupa1nI Propyl acetate I'proup11'reslt1tI Ethylacetate 1'eg11'res1t1tI Butane 1'bju:telnI Butyl alcohol I'bju:tll 'relkaholI Diethylene glycol Ida1'eG111:n 'gle1koulI Dlethyl sulphate I~al'ee11 'BalfeitI ., , Diethyl sulphite Ide1 eel1 sa1faltI D1et~yl sulphIde Ida1'eGl1 'sslfaldI , , ~\.l ~ 1sobutylamine I~aleou bju:tl1 e~lnI , .. "-' Amyl alcohol I rem11 relkeholI." = Propylacet!it Octan ethylnati Buten Butylalkohol Dlethy1englykol D1etb,ylsulflit D1etbylBult'1 t Dlethy18~1d I80butyl~m1n Amylal.koho1 Hexachlorobenzene I,heksa 'klo:rol1'benz1:nI , ., Pentachlorobenzene I,penta klo:rou benzilnI Benzene I'benzl:nI He~echlorben£en' Pentechlorbenzen Benzeh' Chloroenll1ne Chloran1.11h I'klo:rol1'renl1s1nI N1troan111ne l'na1trou'ren11alnI Phenol I'f1:nol1 Nltroenl1ln Fenol Aniline I'renila1nI Hexene I'heksl:nI Hexane I'hekse1nI Ar;llln Hexonol ._ Hexen Hexan Hexanol I'heksnnoUlI Benzonitrile I'benzou'nsltrail1 Benzaldehyde Benz01c ac1d I'benz'reldahsldI Iben' zol1c 'resid! I-rilI Benzoni Toluene 1'toIJul:nI Benzyl alcohol I'benzl1 'relkaholI ,'1'0 loon Heptane Styrene Heptan Styren I'heptelnI I'etalrl:nI trll. Benzaldehyd KYeellna benzoov' Benz.yls1koho1 Ethylbenzene I'eGl1'benzl:nI N-Ethylanillns"I' eell,'reni1aIr1I N-eth;ylan1l1n Caprll1cacId I~ Kyselina Octane I'oktelnI , , rl1Ik resid! " , , Propylbenzene Ethylbenzen kapry10v' Oktan I proupil benzI:nI , , Isopropylbenzene I,aleou proupeI1 benzI:nI ,: , Benzyl acetate I benzI1 ree1titI Nonane I~nounelnI ~opylbenzen Naphtalene Hsfta1en I'nrettali:nI Butylbenzene I'bju:taII'benzi:nI , , , Tert.Butylbenzene I t9:~arl bJu:ta11 benzl:nI Ethyl benzoylacetate I'eGl1 'benzoil'resltltI Biphenyl Fluorene 1beI'fl:naI11 1'fluorl:nI Benzo~henone I'benzou'fl:~unI " " Ieopropylbenzen ~enzy1ecet't Honan Butylbenzen Terc.buty1benzen Benzollscetlitethylneti Difenyl Fluoren Benzofenon E Anthracen Bendl . An''"'IHHme I 'renGr~si: nI "UIIMU IbenzilI; Ibenza11I 13 - tIOMr::ABBREVIATIONS IN COMMONUSE IN ~HOOSTRY THEIR WAY OF READING _~"Wr===========~============================================================== 8. Pf'Qt.o. acid fj 1. alcohol kyselina I':r:sidI acetic acid Ia'si:ti1c'residI I'relkaholI kyselina octovti alkohol , amorphous Ia mo:fasI Amnr, , omorph. 'lfIh. nnQydrous ~n'h8idrasI amorfn:! .HJ. aqua I'rekwaI; aqueous water I'wo: t~I vodny' voda A~.No. At.Wt. b.p. oone. 0., dec. dU. dtlJo~. di.t. atomic number Ie tomik nambaI , , 'yop. evaporation i., lnsol. insoluble Uq. p.Clol. 801. ttp.wt. 'Ubl. m.r. liquid YOC. 80°c ,. atomic . weight I'eikw1asI' ,.: Ia tomik " . bezvody atomov~ wei tI bod V8ru boiling point I boili~ pointI concentrated I'konsentre1tidI decompose koncenirovan1 rozloU t I,di: kem'pouzI !-edit dilute Idai'lju:tI . . -, . dissolved Id1 zolvdI distilled rozpu~tenj Idis't11dI , destllov8nj vypafovan:! Ii,vrepa'reiiianI . ,. tekuty, kapalnY ~aste~ne rozpustn1 partly soluble l'pa:tli 'eoljublI soluble I'soljublI rozpustn1 , -,. , specific weight Ispesifik sublime Isa'blaimI , , , specificka v~ weit! subl1movat , melting point I me~ti~ vacuum I'v~kjuamI bod tan:! pointI . vakuulI1 -. twenty degrees Centigrade , - , I twent1 d1 gr1:z 'sentigreidI above Ia'bavI , below 00 Ibi IoU! soluble in all proportions 200C vy~e nHe , pro' po: ~anzI , nerozpustn1 . Iin soljublI 1 likw1dI . ~islo atomovti vaha l'soljubl in '0:1 rozpuetn1 pomeru v jak~mko1i Appendix 12 Naming chemical compounds In this book the authors have used the systematic names recommended by the commissions of the International Union of Pure and Applied Chemistry (IUP AC) and the rules relating to these names. Because there is a variety of practice in different countries, and within different countries, in the use of chemical names, an appendix is included here which gives the more common of the changes from the traditional unsystematic names formerly used to the present IUP AC recommendations. Rules for naming inorganic compounds Metal ions a) Metals of fixed oxidation state: the name, by itself, of the metal is used. For example: sodium nitrate; aluminium chloride. b) Metals of ~ariable oxidation state: a Roman numeral is used after the name of the metal to indicate its oxidation state. For example: FeCl2 iron (II) chloride FeCI3 iron (III) chloride CuCI copper (I) chloride Acids and their ions a) Binary. acids retain the systematic ending -ide for their ions, e.g. chloride, bromide ions. b) Oxoacids (acids containing oxygen) and their ions are described in terms of the oxidation number of the non-metal forming the acid. If the non-metal has a fixed oxidation number, the name by itself is used. Formula of ion Recommended name Former name CO~carbonate carbonate CIO) chlorate (V) chlorate ClOchlorate (I) hypochlorite NO)" nitrate (V) nitrate N02" nitrate (III) nitrite PO~phosphate (V) orthophosphate SO~sulphate (VI) sulphate S05sulphate (IV) sulphite c) The corresponding acids are named from the ions, with the exception of binary acids. Formula of acid Recommended name Former name HCI hydrochloric acid hydrochloric acid HCI03 chloric (V) acid chloric aCid HCIO chloric (I) acid hypochlorous acid HN03 nitric (V) acid nitric acid HN02 nitric (III) acid nitrous acid d) The oxoacids of metals and their ions are described in terms of the oxidation state of the metal. For metals of fixed oxidation state, the Roman numeral indicating the oxidation state is usually omitted. . n Appendix 12 / The names of the ions are formed in the following way: i) In the anion the ending of the name of the metal (-ium) is replaced by the ending -ate, e.g. aluminium becomes aluminate chromium becomes chromate manganese becomes manganate or ii) the ending -ate is added to the name of the metal, e.g. zinc becomes zincate or iii) the following exceptions are made to the rule: copper becomes cuprate (from cuprum) gold becomes aurate (from aurum) iron becomes ferrate (from ferrum) lead becomes plumbate (from plumbum) silver becomes argentate (from argentum) tin becomes stannate (from stannum) EXAMPLES: Formula of ion CrO~Cr20jMnO~Mn04 Sn05SnO~ZnO~- Recommended name chromate (VI) dichromate (VI) manganate (VI) manganate (VII) stannate (IV) stannate (II) zincate Former name chromate dichromate manganate permanganate stannate stannite zincate inn, (\r or"lIn~ nf :ltrU11(; ~tt~rh,...d ,,, °1 'r,'Ontr.,I' "JItn"" ':)r~ 12 alphabetical order with numerical prefixes giving the number Of such ions or groups. Water is indicated by the word 'aqua'. EXAMPLES: Formula [Cu(4H20)P+ Recommended name tetraaqua copper (II) ion Former name hydrated cupric ion (tetra)potassium potassium hexacyanoferrate (II) ferrocyanid~ (tri)potassium potassium ferricyanide hexacyanoferrate (III) sodium Na2Fe(NO)(CNh( di)sodium pentacyanonitrosylnitroprusside ferrate (II) [Cu(NH)4]S04 tetraammine copper (II) cuprammomum . sulphate (VI) sulphate Non-metal compounds When the stoichiometrical proportions of a molecule are known, the proportions are shown by Greek nU{T1ericalprefixes; in some cases, the prefix mono- is not used. If discrete molecules of a compound have a doubtful existence, then the oxidation number of the least electronegative element is indicated by a Roman numeral. EXAMPLES: . Salts, other than binary compounds a) The folIowing examples indicate the use of numerical prefixes in describing compounds: Formula Recommended name Former name NaHS04 sodium hydrogen sulphate sodium bisulphate Na2HP04 disodium hydrogen sodium hydrogen phosphate (V) orthophosphate calcium hydrogen calcium bicarbonate carbonate ferrosoferric oxide iron (II) diiron (III) oxide (magnetic oxide of iron) Na)P04 trisodium phosphate (V) sodium orthophosphate b) Hydrates are indicated by adding a hyphen to the name of the anhydrous substance, then an Arabic numeral stating the stoichiometric proportion of water, folIowed by a hyphen, and then the word 'water', e.g. CaS04, iH20 is calcium sulphate (VI)-i-water CuS04, 5H20 is copper (II) sulphate (VI)-5-water When the extent of hydration is not known, or uncertain, the term 'hydrated' is placed before the name of the anhydrous substance. c) Complex ions, coordination compounds Th,.. Appendix 1~C't~I~;n Formula C02 CO N20 NO N02 Recommended name carbon dioxide carbon monoxide dinitrogen oxide nitrogen oxide nitrogen dioxide S02 SO) N204 S2Cl2 S02Cl2 sulphur dioxide sulphur (VI) oxide dinitrogen tetroxide disulphur dichloride sulphur dichloride dioxide phosphorus trichloride phosphorus pentachloride . PCI) PCls Former name carbon dioxide carbon monoxide nitrous oxide nitric oxide nitrogen dioxide (nitrogen peroxide) sulphur dioxide sulphur trioxide nitrogen tetroxide sulphur monochloride sulphuryl chloride phosphorus trichloride phosphorus pentachloride Metallic oxides Na202 sodium peroxide sodium peroxide Mn02 manganese (IV) oxide manganese dioxide Cr20) chromium (III) oxide chromium sesquioxide Rules for naming organic compounds Systematic names These names are built up by joining sylIables derived from the following rules: a) A sylIable is used to denote the number of carbon atoms in the lon~est unbranched carbon chain in the compound. The number of Appendix Formula CH)COOH CH)CH2CH2COOH CH)CH2CH.NH2COOH CH2CICH2CH. NH2COOH COOH.COOH CH(OH)COOH.CHOH. COOH CH2COOH.CH(OH) COOH.CH2COOH Recommended name ethanoic acid butanoic acid 2-aminobutanoic acid 2-amino-4chlorobutanoic acid ethanedioic acid 2,3-dihydroxybutanedioic acid 2-hydroxypropane1,2,3-tricarboxylic acid octadecanoic acid hexadecanoic acid octadec-9-enoic acid C17H)SCOOH CISH)ICOOH CH)(CH2),CH= CH(CH2)7COOH Other aliphatic compounds Formula Recommended name C2HsNH2 ethylamine C2HsNH)CI ethylammonium chloride CH)CONH2 ethanamide CH)COCI ethanoyl chloride CH)C~ CH)CO C2HsCN C2HsNC C2HsN02 C2HsSH Former name acetic acid butyric acid a aminobutyric acid 01'10, oxalic acid tartaric acid chlorobenzene benzene'carboxamide benzamide nitrobenzene nitrobenzene l,2-dichlorobenzene orthodichlorobenzene l,3-dinitrobenzene' metadinitrobenzene lA-dichlorobenzene paradichlorobenzene benzene-l,2dicarboxylic acid phthalic acid benzene-l,3-diol resorcinol methyl benzene toluene l,3-dimethylbenzene metaxylene 2-hydroxybenzenecarboxylic acid salicylic acid citric acid stearic acid palmitic acid oleic acid Former name ethyl amine ethylamine hydrochloride acetamide . acetyl chloride . ethanoic anhydride acetic anhydride propanonitrile isocyanoethane nitroethane ethanthiol ethyl cyanide ethyl isocyanide nitroethane ethyl mercaptan @ OCHO chlorobenzene r {amino ('-chloro butyric acid Aromatic compounds a) Aromatic compounds without side chains are named with benzene as the root with the following prefixes and suffixes to indicate functional groups. With two substituted groups~Jthe carbon atom of one group is labelled I, and the others 2-6 resp'ectively, with the second or third group placed as close as possible to the first group. If the side chains form homologues of benzene, the compounds are named as alkylbenzenes. The following examples illustrate these rules. Recommended name Former 'name Formula C,H, ethylbenzene ethyl benzene Q)COOH -- ~I'r 12 benzenecarboxylic acid benzoic acid benzenecarbaldehyde benzaldehyde a to a COOH OCOOH OH OOH OCH, b) Aromatic compounds with side chains containi~g functional groups are named as phenyl substituted aliphatic compounds taking C6HSas the phenyl group. The name thus recommended places emphasis on the part of the structure most likely to take part in reactions. The following examples illustrate these rules. Formula Recommended name Former name OOH phenol (compare benzenel,3-diol) phenol xxxix xxxviii I __. 1-11 AppendIX Appendix l.l carbon atoms thus formulates a saturated hydrocarbon and the specific compound is regarded as a substituted hydrocarbon. The systematic syllables are: Syllable: meth- eth- prop- but- pent- hex- hept- oct- non- decNo. of C atoms: I 2 3 4 5 6 7 8 9 10 b) A syllable Bond: Syllable: c) A syllable Formula -C"H2n+ I -OH -CHO =CO -COOH -Cl - NH 2 -CONH2 7-0 -C to indicate the type of bond between the carbon atoms: single double triple -an-en-ynto indicate a functional group: Group name Syllable hydrocarbon chain -yl alcohol -01 aldehyde -al ketone -one -oic acid carboxylic acid -carboxylic acid chloride chloro' -amine ammo . . ammoamide -amide { { acyl halide -oyl halide nitrile (cyanide) nitro mercaptan -onitrile nitro-thiol Hal -C=N -N02 -SH Hydrocarbon chains In a branching chain, the syllable for the number of carbon atoms is joined to the syllable -yl; e.g. methyl; ethyl; propyl. The carbon atom in the longest chain, to which the branch chain is bonded, is numbered, for hydrocarbons, from either end, and this number is indicated by an Arabic numeral placed in front of the branch chain syllable. For carbon chains possessing a functional group, the carbon atom attached to the functional group is numbered 1, and the remaining atoms in the chain are then numbered consecutively. Example of a branched chain hydrocarbon: CH)CH2CH(C)H7)CH2CH2CH) 3-propyl hexane or 4-propyl hexane (6 carbon atoms in the longest chain, so a substituted hexane; the branch chain is attached to the 3rd atom from one end or the 4th from the other.) Example of a branched chain substituted hydrocarbon: CH)CH2CH(C)H7)CH2CH2CH20H 4-propyl hexan-I-ol (Substituted hexane; numbered 1 from the carbon atom in the functional group of an alcohol; -1-01shows the functional group; 4-propyl indicates the branch chain.) Halogen compounds a) Greek prefixes are used to indicate the number of halogen atoms, except for a monosubstituted compound, e.g. xxxvi 12 Formula Systematic name Former name CH)CI chloromethane methyl chloride CH2CI2 dichloromethane methylene dichloride CHCI) trichloromethane chloroform CCI4 tetrachloromethane carbon tetrachloride CH)Br bromomethane methyl bromide CH)I iodomethane methyl iodide b) Arabic numerals are used to denote the carbon atoms in the carbon chain, to which halogen atoms are bonded, e.g. Formula Systematic name Former Name CH2Br 1,2-dibromoethane ethylene dibromide I CH2Br CHBr2 l,l-dibromoethane ethylidene dibromide I CH) n-propyl chloride C)H7Cl l-chloropropane isopropyl iodide CH)CHl.CH) 2-iodopropane Alcohols Homologous series of primary, secondary, and tertiary alcohols are given systematic names as below: Former name Formula Systematic name methyl alcohol CH)OH methanol ethyl alcohol C2HsOH ethanol propyl alcohol C)H70H .propanol isopropyl alcohol CH)CHOH.CH) propan-2-01 isobutyl alcohol CH)CH.CH)CH20H 2-methyl propan-I-ol ethyl glycol ethan-l,2-diol propan-l,2,3-triol glycerol Aldehydes and ketones Formula Systematic Name Former Name HCHO methanal formaldehyde CH)CHO ethanal acetaldehyde C2HsCHO propanal propaldel;1yde (CH)hCO propanone acetone Carboxylic acids Homologous series of carboxylic acids, and substituted acids, are given systematic names as below. When numbering carbon atoms, that of the carboxyl group is taken as 1, e.g. n:xvii DI Appendix 12 o I C phenyl amine aniline phenylethanone acetophenone phenyl methanol benzyl alcohol phenylethene styrene diphenylmethanone benzophenone methoxybenzene anisole -\.J 6 OQOi, Fused aromatic rings The terms naphthalene and anthracene are used. xxxx